I think 5 looks best, with not a lot of colorful stuff, the orange sticks out nicely and not too much, but I would maybe darken the light grays too. Also if you go for that one, maybe extend the orange of the top part to go over her other shoulder or just make sure it's visible in final, to have a bit of orange in two parts/areas. Some thoughts
I think no. 2 is the most appropriate choice, but it needs a little rework. No. 3's pose is more of a defensive position compared to no. 2. If the champion is a defender, I think you should take the pose from no. 3 and try to incorporate it into no. 2 so it doesn't take up too much space in the composition.
I like your character design. Simple but distinctive. The cape looks sweet. ^^
I took some recommendations from @Oceane_Roh , @arcalie and @tj-works, to make a new sketch and define some parts!